Contents
Introduction
This Module details the requirements for storage of carbon as biochar in the built environment, including reversal risk and durability. Within this Module, a built material is defined as a product used in the construction of buildings or infrastructure projects, including concrete, cement, and asphalt. Durability refers to the stability of CO2e stored as biochar in the built material and the length of time for which CO2 is removed from Earth's atmosphere. Within this Module, concrete durability is used to refer to the structural durability of concrete. This Module is intended for use in conjunction with other Isometric Protocols and Modules, and assumes the following:
- The full quantification of the net tonnes of CO2e removed for Crediting follows the Isometric Biochar Production and Storage Protocol.
- All environmental and social safeguards have been followed according to the ESS Section in the Biochar Production and Storage Protocol and this Module.
This Module applies to biochar that is physically incorporated into conventional built materials (e.g., concrete and asphalt) during their manufacture. It does not apply to CO2 stored in built materials as carbonate minerals, which is addressed by the CO2 Storage via Carbonation in the Built Environment Module. Where a built material both incorporates biochar and stores CO2 through carbonation, only the carbon stored as biochar is Credited under this Module.
The durability horizon for biochar in built materials is 200 years, and Crediting under this Module is limited to the inertinite fraction of the biochar, quantified by random reflectance against the inertinite benchmark1 and refined to the recalcitrant fraction by thermogravimetric analysis2. The horizon is shorter than the 1,000-year default applied elsewhere by the Isometric Standard, and the grounds for it are specific to biochar rather than general to built materials. Containment over 1,000 years is neither guaranteed nor observable for this pathway because the fate of the material through demolition, recycling, and end-of-life reprocessing across that span is extrapolated rather than documented. Biochar is also exposed to the pore solution of a cementitious matrix during encapsulation, typically at pH 12.5 to 13.53, which alters its structure4. While the material remains intact this is not itself a carbon loss pathway, but altered and aged carbon is more susceptible to oxidation5, so the exposure may leave the biochar more vulnerable to degradation once the material is broken up and the carbon is exposed to the open environment. A 200-year horizon corresponds approximately to the design life of a built asset, indicatively 50 years for common buildings and 100 years for monumental structures and bridges under EN 1990:2023, plus reuse.
The stability of carbon within the built environment, and thus its durability, depends on interactions with the surrounding environment and the intended use case. Built materials used in the construction of buildings or infrastructure Projects may be exposed to variable environmental conditions during their use life. Risk factors that may affect the expected durability of built materials include, but are not limited to, interactions with acidic fluids such as acid rain and low-pH groundwater, building fire, abrasion, comminution during recycling, and high-temperature closed-loop recycling of concrete. For the purpose of this Module, built materials are treated as an open system storage mechanism. Reversal risk over the durability horizon is assessed on a Project-specific basis and applied as an uncertainty discount, as set out in Appendix A: Reversal risk.
Biochar storage in the built environment is a novel CDR approach, so this Module incorporates requirements that may be more stringent than some current relevant regulations or other Protocols related to biochar for CDR. This Module will be reviewed when there is an update to scientific published literature that would affect net CO2 removal quantification, durability claims, or the monitoring guidelines outlined in this Module. Future versions of this Module may be altered, particularly regarding requirements for demonstrating durability of biochar, as the stability of carbon in biochar is better demonstrated and documented; quantification of biochar degradation is further improved and refined; and the overall body of knowledge and data regarding all processes, from feedstock supply to conversion and to permanent storage, is significantly increased.
Projects seeking Credits for biochar stored in the built environment are subject to the requirements set out in Applicability and Biochar Characterization, and to the reversal risk assessment set out in Appendix A: Reversal risk.
Applicability
This Module is applicable to Projects that store CO2 in the built environment in the form of biochar incorporated into built materials. The following products are applicable under this Module:
- Concrete, in which biochar is incorporated as:
- Asphalt, in which biochar is used as an aggregate or a modifier, and in which the resulting mixture is laid in a sub-surface layer. Biochar in asphalt surface courses is not creditable, as set out in Asphalt Layer Eligibility.
- Other building materials, for example concrete bricks, roof tiles, and plasters, may be considered under this Module if the Project Proponent can demonstrate sufficient similarity in material life cycles to those presented in Appendix A: Reversal risk. This evidence will be audited by Isometric and the VVB and must be included, with full justification, in the Project Design Document (PDD).
Projects seeking Credits under this Module must meet the following criteria:
- Built materials produced with incorporated biochar must meet the same performance requirements as a conventional product for the intended use case. Any required admixtures or processing steps must be standard industry practice and must not result in disproportionately greater resource use or emissions compared to conventional materials.
- Built materials produced with incorporated biochar must not require additional products or activities related to installation and maintenance as compared to conventional products.
Asphalt Layer Eligibility
Only biochar incorporated into asphalt that is laid in a Sub-Surface Layer is creditable under this Module. Biochar in a surface course is not creditable.
The Project Proponent must identify the layer in which the biochar-amended mixture is laid against a recognized pavement-layer convention. Sub-surface placement must be evidenced for each mass of biochar claimed, to the standard set out in Monitoring Requirements. Biochar mass for which sub-surface placement is not evidenced is treated as surface-placed and is not creditable.
Projects that are explicitly not applicable under this Module include:
- Projects storing CO2 in the built environment in the form of carbonate minerals.
- Projects incorporating biochar into an asphalt surface course.
- Projects incorporating biochar into an unbound pavement layer, including granular subbase and capping.
- Projects incorporating biochar into bituminous surface treatments, including chip seals, surface dressings, sprayed seals, slurry seals, micro-surfacing, cape seals, sand seals, fog seals, and Otta seals. A bituminous surface treatment is a thin, sacrificial layer applied to an existing pavement for preservation or maintenance, in which binder is applied to the existing surface and covered with aggregate, rather than a plant-produced asphalt mixture laid as a pavement layer. These treatments are excluded as a class because they are thin, directly trafficked, short-lived, disperse rapidly and near-completely, and carry the weakest basis for quantification and verification.
Background
Biochar
Biochar is a durable carbon-rich solid material produced from the pyrolysis of waste biomass. The carbon content in biochar can be further separated into stable (with inertinite as a proxy) and degradable (labile) fractions. These distinct carbon fractions have different carbon durabilities, with the stable fraction of biochar being stored durably for a time horizon of 1,000 years and above1 while the labile fraction can degrade over shorter time horizons in the range of a few years to decades, when used in conventional soil amendment applications13 (see Isometric Biochar Production and Storage Protocol). Different production processes and feedstocks directly impact biochar's quality and stability, as they may result not only in variations in the proportions of labile and fixed (stable) fraction but also changes in biochar structure.
Biochar in the built environment is subject to two categories of process. The first is physical liberation and dispersal: loss of fines, particle size reduction during reuse or recycling, and abrasion of the host material. This acts on the biochar regardless of which carbon fraction it belongs to. The second is chemical and biological degradation, including natural mineralization, photodegradation, and leaching driven by water flow or freeze thaw cycling14. This acts principally on the labile fraction, and only once that fraction is exposed.
This Module Credits the stable fraction only. The physical processes that liberate biochar from the host matrix are therefore the dominant determinant of durability, and they are the basis for the inertinite retention factor set out in Appendix A: Reversal risk. The stable fraction is durable over geological timescales once formed1; the question this Module answers is not whether that carbon degrades in place, but whether it remains held within the built material.
In recent years, the incorporation of biochar in construction materials has been receiving increasing interest, owing to its unique properties such as porosity, high specific surface area, water retention capacity and organic carbon content. Biochar's unique structure and porosity makes it a versatile and innovative material that can be utilized in multiple applications including concrete, asphalt, bricks, tiles, insulation materials8, composites, panels, plasters and geopolymers. These uses not only contribute to permanent carbon removal but may also enhance specific material properties15.
Previous studies have focused on integrating biochar in construction materials as a substitute, filler, additive or modifier, mainly in concrete and asphalt production9,15. Applications that have gained traction include biochar used in:
- Concrete production process as an aggregate replacement15
- Cement production as a filler material, reducing the amount of carbon intensive clinker and concrete
- Asphalt applications used as an asphalt modifier and/or binder16
These applications are discussed in further detail in the Built Environment section.
Additional Removal Potential
New research on biochar stored in built materials has shown that these novel materials may capture additional CO2 from the air, particularly in the case of biochar-cement composites17. Replacement of the aggregates in concrete production with biochar improves pore size distribution15 and can enhance the CO2 carbonation process and increases concrete's ability to sequester carbon7.
At the time of writing, there is not sufficient evidence to include this in the quantification framework for net CDR achieved by biochar storage in the built environment. This will be revisited in future editions of the Module as new evidence is published and/or presented to Isometric by Project Proponents as proof of quantification.
Built Environment
Concrete
Concrete, made from cement, sand, aggregate, water, and chemical admixtures, is the most widely used construction material in the world, with approximately 4.2 billion tonnes of cement produced globally in 2020 (Global Cement and Concrete Association, Cement and Concrete Around the World). Compared to other structural materials, concrete has a relatively low cost and embodied carbon, while also providing strength, durability and adaptability. However, because of the large volume of concrete produced and used globally, the concrete supply chain has a large carbon impact, accounting for approximately 5 to 8% of total global CO2 emissions18. The vast majority of emissions during concrete production result from manufacturing Portland Cement (PC) via calcination. During this process, crushed limestone (CaCO₃) is heated in a kiln to high temperatures (~1400°C), causing degradation to CaO (lime) and CO2:
(Equation 1)
Though a portion of emissions are associated with processing limestone and heating the kilns, approximately half of the process emissions are the result of direct emissions from calcination19.
Using less material in the built environment and using lower embodied carbon alternatives to PC both play a key role in efforts to reduce the climate impact of the construction industry. Several recent studies (summarized well in Legan et al.17) have shown that addition of biochar in building materials, notably cement, can improve several key performance indicators while reducing the environmental impact of concrete production. For example, researchers have observed enhanced mechanical properties of biochar-amended concrete, including compressive, flexural and tensile strength; thermal stability and conductivity; bulk density; ductility; flowability; water absorption and penetration potential; and albedo20. However, some studies have also noted decreased flexural strength20 and decreased compressive strength6,9 at biochar dosages up to 40% by mass of cement.
Limits to the amount of biochar addition in construction materials are dictated from material specification and performance standards, especially in terms of the fresh and hardened mechanical properties of concrete and other cementitious composites. The impact on the mechanical performance and other properties is dependent on the biochar type (e.g., feedstock used, temperature of production, post-processing), percentage of biochar incorporated, and concrete mix design. Previously reported limit values of biochar in built materials ranged from 0.5 to 40%17, although these thresholds can vary depending on the material and application. Biochar is typically added at rates of up to 20% and 15% in concrete and asphalt production, respectively21,22,23.
Asphalt
Asphalt is a viscoelastic material that is commonly used in pavement construction, roofing and other building applications24. It is a composite material typically including a mixture of aggregate materials, such as crushed stone, sand and gravel, bound together with bitumen, a highly viscous material derived from petroleum. Asphalt production requires significant energy consumption and is consequently an emissions-intensive process25. Conventional methods of asphalt production are referred to as 'hot-mix asphalt', in which aggregates are heated to remove moisture and are combined with bitumen at high temperatures (typically 170 to 190°C)26.
Several alternatives to hot-mix asphalt have been proposed to reduce the environmental impact of pavement construction. These include warm-mix asphalt, which produces a similar product at lower temperatures (130 to 150°C)25; recycled asphalt pavements; and bio-asphalt, which encompasses both the partial replacement of fossil fuel-derived bitumen with plant-derived bio-oil27 and addition of biochar to the mixture as an asphalt modifier23. Recent studies have shown that addition of modest amounts of biochar can maintain the rheological behaviors and enhance the oxidation resistance of asphalt28, improve deformation resistance23, and inhibit volatile organic compounds (VOCs)29. However, surface asphalt is prone to significant abrasion and loss through tyre wear, and therefore the durability and environmental fate of the biochar is uncertain.
Built Asset Life Cycles
Types of Built Assets and Associated Design Life
Performance requirements for built assets and individual components are influenced by a complex set of factors, including the intended design life, the exposure environment and the mechanical properties needed to meet the requirements of the installation and application.
The design life of a built asset is the assumed period for which it can be used for its intended purpose. Examples of common asset types and design lives (as defined in EN 1990:2023 and CD 226) are summarized in Table 1. Assets with slow rates of change, such as transport or public health infrastructure, will typically be designed with a longer service life and the minimization of maintenance in mind. Corporate office buildings, which are more likely to change in alignment with trends, may be designed with replaceability, adaptability or deconstructability in mind. It is important to note that design life of an asset is not necessarily equivalent to functional service life, which may be longer or shorter than the design life based on a variety of factors such as asset ownership, changes in regional regulatory environments, societal preferences and asset performance. A study of buildings in North America found that the majority of demolished buildings were less than 50 years old30 and the Royal Institute of British Architects highlight that, in the UK, the functional service lives of buildings within the commercial sector are 25 to 30 years31.
Table 1: Overview of common asset types and their design lives as defined in EN 1990:2023 and CD 226.
Asset Type | Design Life (years) |
|---|---|
Monumental building structures, bridges, other civil engineering structure supporting road or railway traffic | 100 |
Building structures, including commercial and residential buildings | 50 |
Asphalt pavement | 40 |
Agricultural (or similar) structures, replaceable structural parts other than tension components | 25 |
Temporary structures (e.g. pavilions, emergency buildings, structures associated with specific sport or art events) | < 10 |
Within a given asset, different components will have different expected design lives. For some element groups, such as the structural skeleton of buildings or the piers of a bridge, which serve the key functional purpose of providing the structure of the asset, the goal is a long service life. Elements with more transient functional requirements, such as internal space partitions, or those prone to disturbance, such as paving over buried services or utilities, will typically have shorter design lives.
Concrete may be used in one or more types of asset throughout its functional life, depending on regional policies and trends surrounding end-state concrete use. This topic is covered in further detail in the Section 3.2.3.2.1 End-State Use Cases (Concrete) . Similarly, asphalt may be recycled into new pavement or other civil engineering projects throughout its functional life (see Section 3.2.3.2.2 End-State Use Cases, Asphalt).
Over the 200-year durability horizon, a built material may pass through one or more construction, demolition, and reuse transitions, and each transition carries a Project-specific reversal risk described in Appendix A: Reversal risk. Concrete is typically recycled at most once as a bound material before reaching a terminal downcycled state, so the number of transitions within the horizon is small. The design life of the asset determines how many transitions occur, and the uncertainty in the location and condition of the biochar increases with each one.
End-State Use Cases
Concrete
Figure 1 summarizes the typical life cycle of concrete, from procurement of raw material, through to processing, use and end-of-life scenarios. In the context of this Module, end-state use case refers to the fate of a given amount of biochar-amended concrete co-located within a single asset after the functional service life of that asset. How concrete is used after the end of an asset's life is influenced by a variety of complex factors, notably the geographic location and the economic and regulatory landscape for particular waste routes. Here, we discuss five possible end-state use cases and implications for CO2 stored within concrete.
1. In-situ Reuse
In-situ reuse refers to extending the use of concrete in its original form. Some level of repair may be required. Because the concrete remains in its original form, it is not subjected to additional reversal risk and stored biochar is considered stable.
2. Ex-situ Reuse
Ex-situ reuse refers to reuse of concrete in its original form, but in a different asset. This is uncommon practice for reinforced structural concrete elements due to the difficulty of extracting these components, lack of demand and the relatively low cost of new concrete. There are greater opportunities for ex-situ reuse with precast concrete elements, as these may be designed to facilitate deconstruction. There are currently limited regulatory frameworks worldwide that incentivize extensive re-use, though some examples do exist (see Norwegian Standard NS 3682). Frameworks currently under development will likely limit concrete reuse based on exposure class, potentially resulting in more extensive reuse of lower performance elements. Because the concrete remains in its original form, it is not subjected to additional reversal risk and stored biochar is considered stable.
3. Closed-loop Recycling
Closed-loop recycling refers to waste processing that occurs in a closed loop, allowing the waste to retain its original value and return to the original production process. Two routes must be distinguished, because they have opposite consequences for stored carbon.
In mechanical closed-loop recycling, concrete is crushed and the recovered material is used as aggregate in new concrete. The biochar is liberated from its original matrix and re-encapsulated, but it is not exposed to conditions that destroy the stable fraction.
In thermal closed-loop recycling, the recovered cement paste is reprocessed to clinker at the calcination temperatures described in Concrete. This destroys the biochar carbon, including the stable fraction. Technologies for thermal closed-loop concrete recycling remain nascent and have not been deployed at scale. At the time of drafting there are a limited number of pilot projects operating at small scale, including in the United Kingdom, France, and Canada, and policy in several jurisdictions is directed toward expanding this route.
Both routes are included in the reversal assessment set out in Appendix A: Reversal risk. Earlier versions of this Module excluded closed-loop recycling from the reversal calculation on the grounds that it was not operating at scale. That exclusion no longer holds over the durability horizon of this Module.
4. Downcycling
Downcycling refers to waste processing where the resultant product has lower value than the original product. This is the most common end-state use case for concrete. Approximately 90% of concrete and demolition waste in the UK is recovered (DEFRA, UK Statistics on Waste)32. The process typically involves crushing of concrete and subsequent use in applications such as road subbase, coastal defenses, engineering fill, and external landscaping. Downcycled concrete may also be used as aggregate in new concrete products where contamination from other waste products is low. But only a low precent of aggregates are reused, and generally the secondary aggregate replacement rates are typically capped in new structural concrete mixes.
Downcycling increases uncertainty about the location of the biochar and exposes additional surface area at the surfaces created by crushing. It does not expose the biochar to temperatures that destroy the stable fraction, and material placed in an unbound downcycled application is not subsequently routed to high-temperature reprocessing, so downcycling is treated as a terminal state for the purposes of the reversal assessment. The biochar is not re-encapsulated, however, and the alkaline pre-conditioning described above applies to it, so downcycled material is not equivalent to biochar that remains held within an intact matrix.
5. Landfill
Concrete is landfilled when it cannot be effectively used in another application through reuse, closed-loop recycling or downcycling. Landfilled concrete can be assumed to remain within a single storage location for long timescales, decreasing geographical uncertainty. However, additional reversal risks may be introduced (e.g. acidic groundwater) depending on regional environmental characteristics and regulations.
Asphalt
A report published by the National Asphalt Pavement Association in 202433 found that 99 percent of reclaimed asphalt pavement (RAP) is recycled, with 93 percent reused in new asphalt pavements and the remainder used in other civil engineering projects, such as unbound aggregate bases. A small percentage, reported at 0.2 percent in 2022, is landfilled where it cannot be used in construction, for example if it contains hazardous materials.
A pavement is built in layers. The surface course is the uppermost bound layer and is in direct contact with vehicle tires. Beneath it sit the binder course, the base, and, where it is bituminous-bound, the subbase. These lower layers are together defined in this Module as the Sub-Surface Layer.
Material is removed from the surface course over time by abrasion caused by friction between tire treads and the pavement, generating tire wear particles (TWP) and road pavement wear particles (RPWP). The road abrasion rate depends on driving conditions and traffic volume and has been reported at 0.04-0.5 mm per year34. A recent study35 found that, for asphalt pavement, wear particle size distributions peaked at 63-106 μm, with 84% of the wear particles falling in the size range of 38-212 μm. Particles at that size are readily transported from the road surface by wind and water, so biochar co-abraded from the surface course disperses to the roadside environment and its subsequent location cannot be tracked.
Biochar placed in a Sub-Surface Layer is shielded from direct tire contact. It is liberated principally when the pavement is milled and reprocessed at end of life, rather than progressively during service. This Module Credits biochar in Sub-Surface Layers only, as set out in Applicability.
Reversal in asphalt is assessed through the liberation and dispersal of biochar during milling and recycling. This is a different approach from the one used for concrete, and both are set out in Appendix A: Reversal risk
Contaminant Exposure Risk Assessment
The Project Proponent must complete a contaminant exposure risk assessment and submit it in the PDD. The assessment must cover the heavy metals and organic contaminants declared under Required measurements, and must be completed for each combination of built material and placement for which Credits are sought.
The assessment must apply a recognized published exposure assessment methodology and must name the methodology applied, so that the assessment is auditable by the VVB. The assessment must be updated and re-submitted when the feedstock, the production process, the mix design, or the placement changes, and at the renewal of each Crediting Period.
The risk of environmental exposure assessment must address, at a minimum:
- Leaching of the declared contaminants from the biochar-amended built material into surface runoff, soil, and groundwater over the service life, assessed using the leaching test methods for construction products given in the EN 16637 series or an equivalent national standard.
- Release of biochar-bearing fines generated by milling, crushing, demolition, or reprocessing of the material, for the expected end-of-life pathway.
- For asphalt, generation of road pavement wear particles where a sub-surface layer becomes directly trafficked following wear of the surface course over the design life of the pavement.
- The receiving environment for released material, including roadside soil, road runoff and stormwater sediment, unbound aggregate applications in direct contact with soil, and landfill leachate, and whether the declared contaminant concentrations present a risk in that setting.
The occupational limb of the assessment must address inhalable and respirable dust, polycyclic aromatic hydrocarbons, and heavy metals across, at a minimum:
- Handling, conveying, and storage of dry biochar at the production facility.
- Blending of biochar into the mix, including at hot-mix asphalt temperatures of 170 to 190°C, where volatile release is greatest.
- Placement of the material, including paving and pouring.
- Milling, crushing, or demolition of the material at end-of-life.
Exposure must be evaluated against the occupational exposure limit values in force in the jurisdiction of each activity, following EN 689:2018 or an equivalent national strategy for testing compliance with occupational exposure limit values.
Where the assessment identifies an exposure risk, The Project Proponent must state in the PDD the mitigation applied, the party responsible for implementing it, and the evidence that it is in place. Mitigation may include a change to the biochar specification or feedstock, a change to the mix design or placement, engineering controls such as enclosure or extraction at the point of handling, or personal protective equipment. Credits must not be issued for material for which the assessment identifies an exposure risk and no mitigation is evidenced.
Required Measurements
As outlined in the Biochar Production and Storage Protocol, there are some potential risks to environmental and human health associated with biochar composition, for example:
- Heavy metals, which may impact soil health and may be transported through groundwater flow
- Contamination by Persistent Organic Pollutants
Project Proponents must include environmental legal and regulatory requirements applicable to their Project in the PDD. In the absence of regulation, the World Biochar Certificate guidelines must be met for storage of biochar in materials for:
- Heavy metals; including Pb, Cd, Cu, Ni, Hg, Zn, Cr, As, Sb, Co, V (declaration of concentration required)
- Organic contaminants; including: a. 16 EPA PAH (declaration of concentration required) b. PCB (0.2 mg kg⁻¹ DM) c. PCDD/F (20 ng kg⁻¹)
Best practice for how to carry out measurements of these parameters is provided by the World Biochar Certificate36, and must be followed by Project Proponents and outlined in full in the PDD.
System Boundaries
Activities that were already occurring and would continue to occur without The Project may be omitted from the system boundary of the GHG accounting, if evidence that the activity was already occurring and would have continued to occur in the absence of the biochar storage activity can be provided.
Emissions associated with upstream and downstream activities associated with the biochar storage process may be omitted from the system boundary if the biochar-amended product meets the same performance requirements as a conventional product for the intended use case and does not require additional products or activities related to product manufacturing, installation, maintenance and end-of-life, as compared to conventional products.
This is based on the assumption that emissions associated with biochar-amended product manufacturing, installation, maintenance and end-of-life would have occurred anyway had a different product been produced and used. The exception to this rule is that additional information is required for exclusion of transport emissions, including transport of biochar-amended built materials to the end-use site (defined as the final location where the biochar-amended product is installed or used). This is to negate the risk of induced transport associated with lower availability of novel biochar-amended products. In order to exclude transport emissions from the system boundary, The Project Proponent must provide suitable justification that transport distances are expected to be within the bounds of national average transport distances for equivalent conventional materials.
Emissions associated with all activities and equipment related to biochar storage in the built environment must be fully accounted for within the Project system boundary. Project Proponents relying on this exclusion must confirm that it applies and provide supporting evidence in the PDD.
Biochar Characterization
The chemical analyses required to assess the reactivity and durability of biochar-C in different storage environments are given in Table 2. Some of these measurements will be used in the quantification of CO2e stored, as outlined in Section 7.0 Quantification of CO₂e Stored. The required and recommended measurements listed below investigate multiple mechanisms of reactivity (or prevention of), including aromaticity and aromatic condensation, functional groups and volatility.
Specific analysis, including heavy metals and PAHs, should be conducted to assess the potential impact of biochar when used in building materials.
Please note that this is not an exhaustive list of analytical methods for each property. If Project Proponents wish to use an alternative, appropriate method of analysis, they may justify its use in the PDD.
Table 2: Requirements for physical characterization of biochar
Property | Threshold | Analytical Method | Description | Monitoring Frequency | Recommended or required? |
|---|---|---|---|---|---|
Total Carbon Content | Standard Test Methods for Determination of Carbon, Hydrogen and Nitrogen in Analysis Samples of Coal and Carbon in Analysis Samples of Coal and Coke ASTM D5373 or Standard Test Method for Determination of Carbon, Hydrogen and Nitrogen in Analysis of Solid Biofuels EN ISO 16948:2015 | The carbon content of applied biochar is necessary for the quantification of Corg and thus CO2e stored, in accordance with Section 7.0 Quantification of CO₂e Stored. See the Biochar Production and Storage Protocol for carbon content sampling guidance. | Measure every production/storage batch as per the guidance in the Calculation of Cbiochar section of the Biochar Protocol. Minimum number of 3 samples per storage batch. | Required | |
Inorganic Carbon Content () | Standard Test Method for Rapid Determination of Carbonate Content of Soils ASTM D4373-02 or Testing of Solid Fuels - Determination of the Carbonate Carbon Dioxide Content DIN 51726:2004-06 | Measurement of inorganic carbon in biochar is required to accurately differentiate Corg from total carbon content, which may include both inorganic and organic forms. Only Corg is credited for under this Protocol and Module. | Measure every production/storage batch as per the guidance in the Calculation of Cbiochar section of the Biochar Protocol. Minimum number of 3 samples per storage batch. | Required | |
Direct mass measurement with calibrated weigh scales | The carbon content of applied biochar is necessary for the quantification of CO2e stored, in accordance with Section 7.0. See the Biochar Production and Storage Protocol for carbon content sampling guidance. | Measure every storage batch | Required | ||
Moisture Content | Standard Test Methods for Determination of Moisture Content in Analysis Samples of Wood Charcoal ASTM D1762-84 or Standard Test Method for Determination of Moisture Content in Analysis of Chemical and Physical Tests of Soil Improvers BS EN 13040:2007 | The moisture content of applied biochar is necessary for the quantification of CO2e stored, in accordance with the Biochar Production and Storage Protocol. Carbon content can be reported on a dry basis to account for differences in total biochar mass. | Measure every production/storage batch as per the guidance in the Calculation of Cbiochar section of the Biochar Protocol. Minimum number of 3 samples per storage batch | Required | |
Random Reflectance () | White-light microscopy, eg ISO 7404-5:2009 | Random reflectance is an indicator of aromaticity, aromatic ring unit size and condensation. A R₀ value greater than 2% has been proposed as a benchmark for quantifying the permanent pool of carbon in a biochar. The R₀ frequency distribution histogram can be used to decide what fraction of biochar above this benchmark can be classified as chemically inert 1. | Measure every production/storage batch as per the guidance in the Calculation of Cbiochar section of the Biochar Protocol. Minimum number of 3 samples per storage batch | Required | |
Reactive Organic Carbon and Residual Organic Carbon () | Thermogravimetric analysis e.g., Hawk, Rock-Eval® or equivalent. The sample is subjected to re-pyrolysis using a standardized heating procedure: it is first held isothermally at 300 °C, then heated at a rate of 25 °C per minute until reaching 650 °C. During this stage, the reactive organic carbon is volatilized and quantified. The remaining material, referred to as “residual organic carbon,” is subsequently measured by combustion at temperatures up to 850 °C. | Measurement of reactive organic carbon in biochar is important because this fraction represents the more labile, easily degradable component of organic carbon. Elevated levels of ROC can reduce biochar’s long-term carbon stability, as it is more susceptible to microbial decomposition and mineralization in soil. Random reflectance values are subsequently only applied to the residual, stable fraction of biochar. | Measure every production/storage batch as per the guidance in the Calculation of Cbiochar section of the Biochar Protocol. Minimum number of 3 samples per storage batch | Required | |
Ash Content | Standard Test Method for the Determination of Ash Content in Solid Biofuels ISO 18122:2022 | Ash is the inorganic portion of biochar that will not volatilize even if combusted | Measure every production/storage batch as per the guidance in the Calculation of Cbiochar section of the Biochar Protocol. Minimum number of 1 samples per storage batch | Required | |
Polycyclic Aromatic Hydrocarbons PAHs, sum of USEPA 16 | Gas Chromatography coupled with Mass Spectrometry (GC-MS) and/or High Performance Liquid Chromatography analysis eg ISO 13859:2014 or BS EN 17503:2022 | Polycyclic aromatic hydrocarbons are organic molecules with fused aromatic rings that can be formed during the pyrolysis process and retained in the biochar. They are chemically stable with a high sorption capacity, known carcinogens and are persistent pollutants that can travel in the environment chain. | Measure at project validation unless feedstock, reactor or process parameters change. Minimum number of 1 sample | Required | |
Heavy metals including As, Cr, Cd, Co, Cu, Hg, Ni, Pb, Sb, Zn, V | Elements As, Cd, Cr, Cu, Ni, Pb, Zn refer to EN ISO 17294-2 ICP - MS standard test method for determination of selected elements. Element Hg refer to ISO 16772:2004 standard test method for the determination of Mercury using cold - vapor atomic absorption spectrometry. Elements Sb, Co, V refer to EN 15411:2011 standard test method for the determination of trace elements | Concentration of heavy metals in biochar is dependent on the feedstock and the process used37. Specific heavy metals have adverse effects and are selected for monitoring38. High concentrations of heavy metals may result in bioaccumulation in biotic systems and increase toxicity in soils and the environment39. | Measure at project validation unless feedstock, reactor or process parameters change. Minimum number of 1 sample | Required |
Quantification of CO2e Stored
Summary
This section details the calculation of net CO2 storage in biochar-amended built materials. The monitoring requirements are set out in Section 8.0 Monitoring Requirements.
Accurate quantification of net CO2 stored requires a robust quantification of associated Project emissions within the project boundary. In the context of this Module, a Project refers to the point of CO2 capture and the point of CO2 storage. This Module defines the point of CO2 storage as the point of incorporation of biochar into a built material. This Module applies only to biochar that is durable for 200 years.
This horizon is shorter than the Isometric 1,000-year default and is specific to biochar in built materials because over 1,000 years the fate of the biochar through demolition, recycling, and end-of-life reprocessing is neither guaranteed nor observable for this pathway, and encapsulation in the high-pH cement pore solution may leave the biochar more vulnerable to loss once the host material is later broken up. The 200-year horizon reflects approximately the service life of the asset plus its first reuse, a period over which fate is documented rather than extrapolated. This is not a claim that built materials are less durable in general.
Projects are required to provide detailed descriptions of Project boundaries for all Crediting activities. Project boundaries must include all areas where removal mechanisms and processes may occur, removed carbon storage locations and forms, and potential reversal and loss pathways.
Quantification of CO2e Removal
Calculation of CO2eStored
(Equation 2)
Where:
- ** is the total CO2 removed from the atmosphere and stored as organic carbon in the biochar for the Reporting Period, , in tonnes of CO2e.
- is the carbon content of the biochar.
- is the dry mass of biochar applied.
- is the fraction of durable biochar that remains in the built material for the full duration of the crediting timeline (200 years), and can be credited under this Module.
- is the mass fraction of carbon dioxide and elemental carbon.
Calculation of Organic Carbon Content
This Module only Credits for the durably stored organic carbon fraction of biochar, which is used to calculate . Thus, is calculated using the following equation:
(Equation 3)
Where:
- is the total carbon content of the biochar as analyzed using the methods described in Table 2.
- is the inorganic carbon content of the biochar as analyzed using the methods described in Table 2, in %.
Please refer to Section 8.3.1 of the Biochar Production and Storage Protocol for full guidelines on number of samples required for the measurement of biochar carbon content, .
Measurement of Mass of Biochar Incorporated
Please refer to Section 8.3.1.1 of the Biochar Production and Storage Protocol for full guidelines on measurement of mass of biochar applied, .
Calculation of
is the fraction of the incorporated biochar credited as durably stored over the 200-year horizon. This Module credits the inertinite (recalcitrant) fraction of the biochar only, quantified by random reflectance and thermogravimetric analysis ().
(Equation 4)
Where:
- is the credited durable fraction.
- is the durable fraction of the biochar over the 200-year horizon.
- is the project-specific durability discount. The fraction of the credited durable carbon that is physically liberated and dispersed to the open environment through wear, comminution, and recycling over the 200-year horizon. It is determined by the reversal risk questionnaire in Appendix A.
Calculation of
The durable fraction is quantified by the random-reflectance inertinite method, following Sanei et al. (2024)1 for the inertinite benchmark, refined by Sanei et al. (2025)2 to credit only the recalcitrant fraction, with the reactive fraction discounted via thermogravimetric analysis. The only difference from that Module is the horizon label (200 years for built materials) and the downstream reversal discount (Equation 4).
As outlined in Section 6.0 of this Module, Project Proponents must report a set of at least 500 measurements of R0, calculated at the maceral-level, for at least three replicate samples of their biochar. Batches that adopt this measurement approach can be credited for the percentage of their biochar which passes the 2% R0 benchmark, as outlined in Sanei et al. (2024)1. The histogram of the R0 values must be submitted at the point of project verification for this Crediting option. This method was further updated in Sanei et al., (2025)2 to refine the methodology to only account for the recalcitrant fraction of biochar (discounting the reactive fraction, determined by thermogravimetric analysis).
To ensure a conservative approach when Crediting biochar durability, we account for uncertainty in both the fraction of biochar passing the 2% R₀ benchmark and the proportion of carbon that is non-reactive. Specifically, for each replicate sample we determine the fraction of R₀ measurements that meet or exceed the 2% benchmark. The credited inertinite fraction is the mean of these fractions across all samples analyzed, reduced by one standard deviation of the fractions (Equation 5). This is applied to the non-reactive carbon fraction, itself reduced by one standard deviation (Equation 6), to give the credited durable fraction (Equation 7). This ensures the durability estimate reflects a lower-bound confidence level, mitigating the risk of overestimating long-term carbon storage.
As such, is calculated through:
Calculating the sample standard deviation of quantifying the typical deviation of individual measurements from their mean, which is used to account for uncertainty and conservatively adjust the estimated durable fraction of biochar carbon, as:
(Equation 5)
Where:
- is the standard deviation of the fractions passing the 2% benchmark.
- is the number of samples analyzed (i.e. ≥ 3).
- is the fraction of R₀ measurements ≥ 2% in the -th sample.
- is the mean of the fractions (≥ 2%) across all samples.
Calculating the sample standard deviation of quantifying the typical deviation of individual measurements from their mean, which is used to account for uncertainty and conservatively adjust the estimated durable fraction of biochar carbon, as:
(Equation 6)
Where:
- is the standard deviation of measurements
- is the number of samples analyzed (i.e. ≥ 3).
- is the individual measurement for the -th sample.
- is the mean of all measurements
Then:
(Equation 7)
Where:
- is the fraction of durable (inert) carbon in the biochar after 200 years, adjusted conservatively for uncertainty.
- is the mean of the fractions (≥ 2%) across all samples.
- is the standard deviation of the passing the 2% benchmark.
- is the mean of all non-reactive carbon measurements.
- is the standard deviation of .
The maximum and minimum functions are applied to ensure that the fractions are bounded.
Calculation of Uncertainty Discount,
is the project-specific durability discount for physical liberation and dispersal of the credited durable carbon through wear, comminution, and recycling over the 200-year horizon. It does not re-discount the labile fraction (which is not credited), the one-standard-deviation conservatism already contained within , or acid and matrix dissolution: acid dissolves the host matrix and can expose biochar, but does not mineralize the inertinite fraction, which is the same basis on which the inertinite fraction is treated as permanent in the Biochar Storage in Low Oxygen Burial Environments Module.
is determined per Project, and per distinct placement or mix design where a Project spans several, by the reversal risk questionnaire in Appendix A. The questionnaire scores placement and incorporation, physical exposure, and end-of-life and recycling factors, applies gating exclusions, and maps the net score to a durability discount band.
The Project Proponent must complete the reversal risk questionnaire (Appendix A) for each placement or mix design, record the supporting evidence for each response in the PDD, and apply the resulting durability discount . The questionnaire must be re-completed at the renewal of each Crediting Period or on material change. A Project that does not complete the questionnaire, or that leaves a variable uncharacterized, receives the worst-case (Very High) discount for that variable.
Calculation of CO2e Counterfactual, RP
For biochar production, the calculation of is determined by the requirements laid out in the Counterfactuals Section of the Biomass Feedstock Accounting Module.
Calculation of CO2e Emissions, RP
is the total greenhouse gas emissions associated with a given Reporting Period, RP.
Equations and emissions calculation requirements for including emissions associated with reactor operations and reaction monitoring, are set out in the relevant Protocol and are not included in this Module. Specific considerations for CO2 stored as biochar in built materials are set out here.
CO2 removals must not be double counted, regardless of the production of product Environmental Product Declarations. The product must still comply with all relevant emission accounting regulations and requirements, which may mean emissions are double counted; however, removals must not be double counted. This is the most conservative approach to take. Crediting claims must be transparently reported and must not form part of marketing for a separate product.
Allocation procedures may be undertaken to separate emissions associated with the concrete production and the emissions associated with the CO2 storage process. Allocation procedures must follow the following emissions allocation procedure:
- Procedure 1: Allocate all emissions to CDR. Projects may opt to allocate all emissions to CDR.
- Procedure 2: Divide the process into sub-processes. Where possible, the process may be divided into sub-processes. For example it may be possible to isolate processes relating to processing and storing CO2 only. Only sub-processes and relevant inputs that are physically separable may undergo division, for example electricity usage for equipment with separate electricity meters. Sub-processes that are physically separable and do not contribute to CDR may be excluded from the CDR system boundary.
Transport emissions must be considered if the average transport distance for biochar-amended built materials is more than the average transport distance of normal products produced by the production facility. All other downstream emissions may be excluded from the system boundary if these activities were already occurring and would continue to occur in the absence of The Project. This can be evidenced by providing documentation that the biochar-amended product meets the same performance requirements of a conventional product for the intended use case, as described under the Section 2.0 Applicability.
Buffer Pool
Projects using this Storage Module are typically deemed to have No Observable Risk of reversal, according to the Isometric Standard Risk Assessment Questionnaire (also found in the relevant Protocol), as all reversal risk is accounted for using the reversal risk modelling and Uncertainty Discount approach. This results in a 0% buffer pool for Projects using this Storage Module. This reversal risk will be reassessed at the renewal of the Crediting Period, or when new scientific research and knowledge are produced.
Monitoring Requirements
The requirements in this section apply to the process steps and equipment within the Project system boundary. Where the exclusion of downstream manufacturing emissions set out in the System Boundaries section is relied upon, the boundary terminates at the point at which biochar or a biochar-containing material transfers to the downstream manufacturer, and process data for the manufacturer's own operations is not required. Requirements relating to the mass of biochar incorporated, the mix into which it was incorporated, and the pavement layer in which it was laid apply irrespective of that exclusion.
Process Requirements
Project Proponents are required to provide detailed information on the end material production process in the PDD. This must include:
- The reactor and equipment description including engineering design diagrams.
- Mass percentage of biochar wt.% incorporated into the final construction material (e.g., concrete, brick, insulation panel).
- A list of all additional materials or admixtures (e.g., superplasticizers, accelerators, binders) that are required as a direct consequence of using biochar, along with an explanation of their function and whether they would be present in the baseline mix design.
- Confirmation of whether the exclusion of downstream manufacturing emissions set out in the System Boundaries section is relied upon.
Process specific details, including energy consumption, curing steps and processing temperatures, are required only where the exclusion of downstream manufacturing emissions set out in the System Boundaries section is not relied upon. Where the biochar-amended product meets the same performance requirements as a conventional product for the intended use case and requires no additional products or activities related to product manufacturing, installation, maintenance and end-of-life, those emissions are omitted from the system boundary and the underlying process data is not required. Project Proponents relying on the exclusion must instead evidence that it applies, in one of three forms:
- A declaration of conformity to the applicable product standard for the intended use case,
- The job mix formula or mix design for both the amended and baseline formulations, or
- An Environmental Product Declaration (EPD) for the amended product.
Where the exclusion is not relied upon, Project Proponents must provide, for each additional or modified process step, the energy consumption, processing temperature and curing regime, together with the emissions allocation procedure applied under the Quantification of CO2e Stored section. Where sub-process energy cannot be metered separately, Procedure 1 (Section 7.2.3) must be applied and all process emissions allocated to the removal.
Irrespective of whether the exclusion is relied upon, Project Proponents must state the maximum temperature to which the biochar is exposed during production of the final material. Where this exceeds 200°C, the release of volatile organic compounds and PAHs must be addressed in the contaminant exposure risk assessment required under the Environmental and Social Safeguards section.
To verify incorporation of biochar into the final product, Project Proponents must provide documentation in the PDD that establishes both the mass of biochar incorporated and the mix into which it was incorporated. Acceptable forms include:
- Production batch records extracted from the producer's automated batching system, stating the mass of each material input per batch and the mix designation produced,
- Bills of sale for biochar-containing admixtures or materials,
- Final product specifications from downstream users, or
- Environmental Product Declarations (EPDs) where available.
Production batch records must identify the issuing facility, the batching system from which they are extracted and the date of extraction, must cover the full Reporting Period, and must reconcile to the Project Proponent's records of biochar dispatched to that facility. For asphalt, the documentation provided must identify the mix designation (e.g., EN 13108 or Superpave) for each batch, so that the pavement layer can be established as required under the Asphalt Layer Eligibility section.
Reactor and Equipment Description
A process flow diagram covering the process steps and equipment within the Project system boundary must be included in the PDD. The diagram must cover the equipment the Project Proponent operates or contracts, including any dosing or feed system installed at the downstream manufacturer's facility, and must terminate at the point at which the material transfers to the downstream manufacturer. Where the exclusion of downstream manufacturing emissions set out in the System Boundaries section is not relied upon, the diagram must also cover the additional or modified process steps at the manufacturer's facility.
The process flow diagram must be prepared to ISO 10628 or an equivalent convention, and must show:
- Each processing step as a discrete unit operation.
- The material inflows and outflows of each step, including waste and loss streams.
- The energy inputs to each step and their source.
- The measurement point and instrument for each metered stream (e.g., flow meters, temperature sensors, weighbridges).
Project Proponents must also provide an equipment list stating, for each item of equipment within the boundary, its function, make and model or asset identifier, and rated throughput capacity.
Process steps should include acceptable processes including, but not limited to:
- Particle size reduction grinding or milling.
- Mixing, stirring or blending.
- Calcination.
- Drying and heating.
Biochar Characterization
Characterization of biochar and ongoing monitoring requirements are outlined in the Biochar Characterization section and must be included in the PDD for validation and subsequently submitted for verification adhering to the sampling frequency requirements.
Storage Site
Though not required, providing specific site information can help demonstrate reduced risk of carbon loss if certain thresholds are met and highlight portions of the material stream that may require additional assessment. This may include:
For asphalt applications:
- Specific uses of
- Traffic density
- Asphalt density
For concrete applications:
- Structural/design lifespan of concrete
- Exposure class (e.g. using EN206 or equivalent)
- Concrete type and strength class
- Application type (examples include but are not limited to foundations, structural, decorative)
- Demolition likelihood or planned obsolescence
- Estimated fraction of returned or unused concrete from construction sites, and its associated end-of-life fate (e.g., landfill, reuse, downcycling)
Compliance With Product Standards
An applicability criterion for Crediting with this Module is that the biochar-amended built materials must meet the same performance requirements as conventional products for the intended use case. Project Proponents are required to demonstrate compliance with the relevant standards for the use case of each mix produced, while also demonstrating the product is comparable to traditional products and results in no additional product use. It is the responsibility of The Project Proponent to clearly demonstrate comparability between produced products and traditional products within the PDD submitted to The Project VVB and Isometric. Standards, methodologies and SOPs that are utilized by a Project Proponent must be clearly outlined and referenced in the PDD upon submission, and deviations from standards must be highlighted.
Built materials produced for the purpose of carbon storage and Credit issuance are expected to meet the required performance standards and criteria for the intended application, as defined by applicable codes or regulations. These materials must be demonstrably fit for purpose and comparable in functional performance to traditional products that would have been used in the absence of the biochar-amended material. This may be achieved through the undertaking of standardized performance testing procedures required in the location the material is utilized. In the absence of local or regional standards related to production and performance criteria, a Project Proponent is required to adhere to International Organization for Standardization (ISO) and/or CEN (the European Committee for Standardization) criteria. The final product should be compliant with relevant product standards such as EN 15804 for Environmental Product Declaration in the construction industry, relevant product classes and quality standards that are applicable.
Evidence and data, resulting from research studies of biochar addition in built materials such as asphalt, cement or other building elements, have shown the potential for additional benefits and improvements on the final product quality9,40,41. Biochar addition can impact a range of different properties (mechanical, chemical and physical properties) including but not limited to the following:
- Flexural strength (N/mm²)
- Sound absorption (Hz) (applicable for concrete and other building elements like insulation or plaster)
- Compressive strength (N/mm²)
- Tensile strength (N/mm²)
- Density (kg/m³)
- Electrical resistance (Ω)
- Sorption capacity
- Fire resistance (fire retardant or fire resistance)
Project Proponents should include any additional product characterization, analysis and reported properties of the final produced materials. Changes or deviations from the baseline product values should also be included and relevant product standards referenced in the PDD Appendix.
Departures from standard may be permissible on a case-by-case basis. Project Proponents seeking a departure from standard must submit documentation on the requested departure and proof of approval by the relevant regulatory body to Isometric and the VVB.
Definitions and Acronyms
- AssetAny tangible or intangible property that has value and can be owned, controlled or utilized by an individual or organization. In the context of this module, an asset refers to a physical structure.
- BaselineA set of data describing pre-intervention or control conditions to be used as a reference scenario for comparison.
- Bio-oilA mixture of water, organic acids, aldehydes, ketones, sugars, phenols, and other organic compounds derived from the thermal breakdown of biomass. Thermal breakdown of biomass is achieved via thermochemical processes, such as pyrolysis, which heat biomass in low- or no-oxygen environments to high temperatures (~e.g. 350-650°C). Bio-oil is often also referred to as pyrolysis oil or bio-crude.
- Buffer PoolA common and recognized insurance mechanism among Registries allowing Credits to be set aside (in this case by Isometric) to compensate for Reversals which may occur in the future.
- Built MaterialA material used in the construction of an asset.
- Carbon Dioxide Equivalent Emissions (CO₂e)The amount of CO₂ emissions that would cause the same integrated radiative forcing or temperature change, over a given time horizon, as an emitted amount of GHG or a mixture of GHGs. One common metric of CO₂e is the 100-year Global Warming Potential.
- Carbon Dioxide Removal (CDR)Activities that remove carbon dioxide (CO₂) from the atmosphere and store it in products or geological, terrestrial, and oceanic Reservoirs. CDR includes the enhancement of biological or geochemical sinks and direct air capture (DAC) and storage, but excludes natural CO₂ uptake not directly caused by human intervention.
- CementA chemical substance used for construction that sets, hardens, and adheres to other materials to bind them together. Ordinary Portland Cement (PC) is the most common cement used in modern concrete. Other types of cement include Ground Granulated Blast-furnace Slag (GGBS), Pulverised Fly Ash (PFA) and natural pozzolans.
- ConcreteA composite material composed of aggregate, cement, sand and water that cures to a solid over time.
- ConversionA retirement pathway in which an existing EAC is retired to enable the issuance of a new EAC with different specified characteristics.
- CreditA publicly visible uniquely identifiable Credit Certificate Issued by a Registry that gives the owner of the Credit the right to account for one net metric tonne of Verified CO₂e Removal or Reduction. In the case of this Standard, the net tonne of CO₂e Removal or Reduction comes from a Project Validated against a Certified Protocol.
- Crediting PeriodThe period of time over which a Project Design Document is valid, and over which Removals or Reductions may be Verified, resulting in Issued Credits.
- Direct EmissionsEmissions that are produced by a specific CDR process and are directly controllable.
- DurabilityThe amount of time carbon removed from the atmosphere by an intervention – for example, a CDR project – is expected to reside in a given Reservoir, taking into account both physical risks and socioeconomic constructs (such as contracts) to protect the Reservoir in question.
- EmissionsThe term used to describe greenhouse gas emissions to the atmosphere as a result of Project activities.
- Environmental Product DeclarationA public document that transparently reports objective, comparable and third-party verified data about products and services' environmental performances from a lifecycle perspective. The EPD is supported by an underlying Life Cycle Assessment (LCA) report, a systematic and comprehensive summary of the LCA project to support the third-party verifier when verifying the EPD.
- Environmental Protection Agency (EPA)A United States Government agency that protects human health and the environment.
- FeedstockRaw material which is used for CO₂ Removal or GHG Reduction.
- Greenhouse Gas (GHG)Those gaseous constituents of the atmosphere, both natural and anthropogenic (human-caused), that absorb and emit radiation at specific wavelengths within the spectrum of terrestrial radiation emitted by the Earth’s surface, by the atmosphere itself, and by clouds. This property causes the greenhouse effect, whereby heat is trapped in Earth’s atmosphere (CDR Primer, 2022).
- International Standards Organization (ISO)A worldwide federation (NGO) of national standards bodies from more than 160 countries, one from each member country.
- Issuance (of a Certificate)Certificates are issued to the Certificate Account of a Project Proponent with whom Isometric has a Validated Protocol after an Order for Verification and Certificate Issuance services from a Buyer and once a Verified Removal or Reduction has taken place.
- Lossesfor open systems, biogeochemical and/or physical interactions which occur during the removal process that decrease the CO₂ removal .
- ModelA calculation, series of calculations or simulations that use input variables in order to generate values for variables of interest that are not directly measured.
- ModuleIndependent components of Isometric Certified Protocols which are transferable between and applicable to different Protocols.
- PathwayA collection of Removal or Reduction processes that have mechanisms in common.
- ProjectAn activity or process or group of activities or processes that alter the condition of a Baseline and leads to Removals or Reductions.
- Project Design DocumentThe document, written by a Project Proponent, which records key characteristics of a Project and which forms the basis for Project Validation and evaluation in accordance with the relevant Certified Protocol. (Also known as “PDD”).
- Project Design Document (PDD)The document that clearly outlines how a Project will generate rigorously quantifiable Additional high-quality Removals or Reductions.
- Project ProponentThe organization that develops and/or has overall legal ownership or control of a Removal or Reduction Project.
- Project boundaryThe defined temporal and geographical boundary of a Project.
- ProtocolA document that describes how to quantitatively assess the net amount of CO₂ removed by a process. To Isometric, a Protocol is specific to a Project Proponent's process and comprised of Modules representing the Carbon Fluxes involved in the CDR process. A Protocol measures the full carbon impact of a process against the Baseline of it not occurring.
- ProxyA measurement which correlates with but is not a direct measurement of the variable of interest.
- RPReporting Period
- RemovalThe term used to represent the CO₂ taken out of the atmosphere as a result of a CDR process.
- ReversalThe escape of CO₂ to the atmosphere after it has been stored, and after a Certificate has been Issued. A Reversal is classified as avoidable if a Project Proponent has influence or control over it and it likely could have been averted through application of reasonable risk mitigation measures. Any other Reversals will be classified as unavoidable.
- StakeholderAny person or entity who can potentially affect or be affected by Isometric or an individual Project activity.
- StorageDescribes the addition of carbon dioxide removed from the atmosphere to a reservoir, which serves as its ultimate destination. This is also referred to as “sequestration”.
- System BoundaryGHG sources, sinks and reservoirs (SSRs) associated with the project boundary and included in the GHG Statement.
- UncertaintyA lack of knowledge of the exact amount of CO₂ removed by a particular process, Uncertainty may be quantified using probability distributions, confidence intervals, or variance estimates.
- ValidationA systematic and independent process for evaluating the reasonableness of the assumptions, limitations and methods that support a Project and assessing whether the Project conforms to the criteria set forth in the Isometric Standard and the Protocol by which the Project is governed. Validation must be completed by an Isometric approved third-party (VVB).
- Validation and Verification Bodies (VVBs)Third-party auditing organizations that are experts in their sector and used to determine if a project conforms to the rules, regulations, and standards set out by a governing body. A VVB must be approved by Isometric prior to conducting validation and verification.
- VerificationA process for evaluating and confirming the net Removals and Reductions for a Project, using data and information collected from the Project and assessing conformity with the criteria set forth in the Isometric Standard and the Protocol by which it is governed. Verification must be completed by an Isometric approved third-party (VVB).
- Waste productAn output of a process that has no intended value to the producer.
Appendix A: Reversal Risk
Biochar Durability Horizon and Storage Uncertainty in the Built Environment
Definition of Storage Uncertainty
This Module credits biochar in built materials over a 200-year durability horizon, rather than the Isometric 1,000-year default. The grounds are set out in full in Section 1.0 and summarized here. They are specific to biochar rather than general to built materials. Containment over 1,000 years is neither guaranteed nor observable for this pathway, because the fate of the material through demolition, recycling, and end-of-life reprocessing across that span is extrapolated rather than documented. Biochar is also exposed to the pore solution of a cementitious matrix during encapsulation, typically at pH 12.5 to 13.53, which alters its structure, including pore enlargement and matrix defectiveness4. While the material remains intact this is not itself a carbon-loss pathway, because there is no oxygen, no export route, and the condensed inertinite core is chemically resistant1. Altered and aged carbon is, however, more susceptible to oxidation5, so the exposure may leave the biochar more vulnerable to degradation once the material is broken up and the carbon is exposed to the open environment. The 200-year horizon corresponds approximately to the design life of a built asset, indicatively 50 years for common buildings and 100 years for monumental structures and bridges under EN 1990:2023, plus first reuse.
A second consideration is the uncertainty in the location of the material at any given time. As with the CO2 Storage via Carbonation in the Built Environment Module, a built material may pass through many use cases across its life, depending on the initial use case, local regulatory requirements, and economic incentives. In the traditional construction industry there has been no need to track built materials past the life of an asset, particularly where elements are designed to perform with minimal maintenance or intervention. Biochar-amended built materials are therefore likely to transition through several construction-demolition-reuse cycles with minimal ability to track these changes. Over the 200-year horizon this leads to uncertainty in both the storage location of the material and, consequently, whether it is exposed to conditions that lead to loss of the credited carbon. This treats built-environment storage as an open system and necessitates the conservative, project-specific approach to reversal set out below.
Biochar Reversal
This Module credits the inertinite (recalcitrant) fraction of the biochar only (Equation 7). That fraction is durable over geological timescales once formed1 and is refined to the thermally non-reactive residual by thermogravimetric analysis2. It is chemically resistant while it remains encapsulated in the host matrix, and while it remains in contained chunks after the matrix is broken up. The reversal concern is therefore not chemical mineralization of encapsulated carbon, but physical liberation of the credited inertinite to mobile fines that are dispersed into oxic surface environments, where the fine, high-surface-area material can then oxidize and dissolve over the horizon5. Liberation happens through wear, comminution, and recycling. The pathways that act on liberated, dispersed material include:
- Physical loss: abrasion or erosion of the material surface, delamination or spalling, and comminution during demolition, crushing, and recycling 42.
- Abiotic degradation: chemical reactions with environmental factors, including natural mineralization, photodegradation, and leaching by water flows and freeze-thaw cycles14.
- Microbial degradation: through the action of aerobic or anaerobic microorganisms and lichen colonization43,44.
Two related mechanisms are handled outside this dispersal term. Acid and matrix dissolution can expose biochar as the host matrix is lost, but does not mineralize the inertinite fraction, so it is treated as an exposure driver in the questionnaire (Section B), not a carbon-loss term. Thermal exposure during hot asphalt recycling (approximately 150 to 190°C) does not destroy the credited fraction, because that fraction is by construction the thermally non-reactive residual determined by thermogravimetric analysis (Equation 7), which is stable well above that range: road-grade biochar loses only about 1% of its mass to 150°C and about 5% to 400°C45, and oxidation onset rises with pyrolysis temperature, well above the hot-mix range46. High-temperature reprocessing of concrete to clinker (approximately 1,400°C, the calcination temperature described in the Concrete background) destroys even the inertinite, and is handled as a gating exclusion (below).
Biochar in Concrete
Liberation of biochar from concrete occurs when the material is lost or broken up, either during use or at end of life. During use, the relevant drivers are surface loss by physical or chemical weathering, including exposure to acid rain and contact with acidic groundwater or soils (most relevant for foundation uses). The end-of-life pathways and their reversal treatment are set out in the Section 3.2.3.2.1 End-State Use Cases (Concrete) background and summarized here:
- In-situ and ex-situ reuse: the material remains in its original form, so no additional carbon is liberated.
- Downcycling (the dominant pathway in most regions): crushing liberates a fraction of the biochar to fines, but the majority remains bound in coarse, re-encapsulated aggregate. Downcycling is treated as a terminal state, though the alkaline pre-conditioning4 applies to the exposed material.
- Mechanical closed-loop recycling: the biochar is liberated and re-encapsulated in new concrete, and is not exposed to conditions that destroy the stable fraction.
- Thermal closed-loop recycling to clinker: reprocessing at calcination temperatures destroys the credited inertinite. This pathway is a gating exclusion (G3): a Project with a credible, unconstrained likelihood of it is ineligible unless a binding, evidenced restriction against it is in place.
- Landfill: the material remains in a single location, reducing geographic uncertainty, though acidic leachate exposure may apply depending on region.
Biochar in Asphalt
Only biochar in a Sub-Surface Layer is creditable under this Module; biochar in the surface course, and in bituminous surface treatments, is an ineligible practice, as set out in the Section 2.0Applicability. Surface-course material abrades directly under tire contact, generating tire and road pavement wear particles at a size (peaking at 63 to 106 μm)35 that is readily transported from the road by wind and water, so the material disperses fully and untraceably into oxic environments34. For creditable Sub-Surface placements, the reversal concern is the biochar comminuted to mobile fines during milling and recycling over the horizon, which is quantified through the questionnaire and the Uncertainty Discount ( derivation below. Exposure to chlorides (road salt) and sulfates (surface water) may increase the reactivity of dispersed material.
Reversal Risk Approach and Calculation of Uncertainty Discounts
Reversal is assessed for each Project using a questionnaire. The net score maps to a banded durability discount, . Each band's value of is derived from a comminution and dispersal model of how the credited inertinite is physically liberated over the horizon, set out under Derivation of the Durability Discount below.
Reversal risk is assessed on a project-by-project basis. The Project Proponent must complete the questionnaire for each Project, and for each distinct placement or mix design where a Project spans several. Because built-environment storage is largely unobservable over the horizon, the output is a durability uncertainty discount on the credited durable fraction ( applied in Equation 4), instead of a buffer-pool contribution. This assessment is conservative by default: any variable not characterized with verifiable evidence is scored at its worst option, and gating answers override the total and can result in ineligibility of the Project.
Note that Projects may choose to provide documentations specific to the region of operations to calculate a Project-specific reversal risk. This documentation may include, but is not limited to:
- Geologic maps of bedrock lithology (from USGS or national equivalent) and groundwater pH.
- Climatic data, including average yearly temperature, precipitation volume and precipitation pH.
- Estimated transport radius of produced materials.
- If this is unknown for a given Project, Project Proponents may use either the maximum possible transport distance or a conservative average distance.
- Types of assets that materials may be used in and a breakdown by percentage.
- Proof of material suitability for the range of applications (e.g. certificates of compliance with concrete quality and performance standards).
- Risk of external acid attack, based on:
- Regional groundwater and precipitation pH.
- Likely exposure risk of the concrete containing stored carbon.
- This can be determined through analysis of possible asset types and well-justified assumptions about the location of the concrete within the asset.
- Chain-of-custody evidence for placement, or, where unavailable, a probability analysis of the concrete or asphalt end-state based on regional trends.
The Reversal Risk Questionnaire
Table A1: Gating Crtiera.
Ref | Gating question | If yes |
|---|---|---|
G1 | Is the biochar in a bituminous surface treatment, or in a surface course? (see Section 2.0Applicability) | Ineligible |
G2 | Can the Project provide layer-constraining product evidence (job mix formula or EN 13108 / Superpave designation for asphalt; element and mix specification for concrete) tying the biochar mass to its placement? | If no, score the volume at the worst option in every question |
G3 | Concrete: is there a credible, unconstrained likelihood of closed-loop reprocessing to clinker (approximately 1,400°C, destroying even the inertinite), with no binding restriction against it? | Ineligible or Very High unless mitigated by D1 |
Table A2: Section A (placement and incorporation).
Ref | Factor | Response option | Points |
|---|---|---|---|
A1 | Placement within the built element | Asphalt, Sub-Surface base course | 0 |
Asphalt, binder or intermediate course | 2 | ||
Asphalt, surface course | Not eligible | ||
Concrete, thick structural or foundation | 0 | ||
Concrete, above-ground building element | 2 | ||
Concrete, thin element (brick, facade panel, paving, tile) | 4 | ||
A2 | Incorporation route (degree of encapsulation) | Fully encapsulated (binder modifier; cementitious matrix, filler, or SCM) | 0 |
Aggregate substitute | 2 | ||
Coarse or functional-layer incorporation (exposed) | 3 | ||
A3 | Placement evidence quality | Product-level evidence plus batch reconciliation (D2 standard met) | 0 |
Buyer attestation only | 2 | ||
None (also triggers G2) | worst-case |
Table A3: Section B (physical exposure over the horizon).
Ref | Factor | Response option | Points |
|---|---|---|---|
B1 | Abrasion or surface-wear exposure (asphalt) | Not surface-exposed (Sub-Surface) | 0 |
Low-volume road or light traffic | 2 | ||
High-traffic highway | 4 | ||
B2 | Chemical exposure (concrete EN 206 class; asphalt de-icing) | Mild (for example XC1, dry or sheltered) | 0 |
Moderate | 1 | ||
Aggressive (XA, XS, XF; low-pH groundwater or acid rain) | 3 | ||
B3 | High-temperature or fire event exposure (asset type and region) | Low | 0 |
Moderate | 1 | ||
High | 2 |
Table A4: Section C (end-of-life and recycling).
Ref | Factor | Response option | Points |
|---|---|---|---|
C1 | Service life before the first end-of-life event | Long (greater than 50 years) | 0 |
Medium (25 to 50 years) | 1 | ||
Short (less than 25 years) | 3 | ||
C2 | Recycling or reprocessing cycles within the horizon | 0 to 1 | 0 |
2 to 5 | 2 | ||
More than 5 | 4 | ||
C3 | Dominant regional end-of-life pathway | Contained (in-situ or ex-situ reuse; downcycle to aggregate or base; engineered landfill) | 0 |
Hot recycling into new material (comminution, re-lay) | 2 | ||
Closed-loop reprocessing to clinker or other high-temperature destruction | Gating G3 / Very High | ||
Unknown | 4 | ||
C4 | Regional recycling rate and policy trajectory | Low and stable | 0 |
Moderate | 1 | ||
High, or rising toward high-temperature reprocessing | 3 |
Table A5: Section D (containment safeguards and mitigants). Subtract from the Section A to C total.
Ref | Mitigation | Response | Points |
|---|---|---|---|
D1 | Binding end-use restriction (for example Sub-Surface only; no closed-loop clinker recycling), enforced by design or contract and evidenced | Yes | −3 |
No | 0 | ||
D2 | Regional regulatory or practical constraint preventing the high-risk pathway | Yes | −2 |
No | 0 | ||
D3 | Monitoring and re-assessment commitment at each Crediting-Period renewal | Yes | −1 |
No | 0 |
Scoring. Sum Sections A to C, then subtract Section D to give the net score. Map the net score to the risk rating and durability discount in the banded discount schedule below (Derivation of the Durability Discount U). A Project that does not complete the questionnaire, or that leaves variables uncharacterized, receives the worst-case discount.
Derivation of the Durability Discount U
is the project-specific durability discount as specified in Equation 4, Section 7. The term also represents the fraction of the credited inertinite that may be physically liberated to mobile fines and dispersed into oxic surface environments over the 200-year horizon. The calculation for does not re-discount the labile fraction, which is not credited under this Module; the one-standard-deviation conservatism is already accounted for in ; or acid and matrix dissolution, which exposes but does not mineralize inertinite1. Thermal destruction (clinker reprocessing) and surface abrasion are handled as gating exclusions, so they are also excluded from the graded discounts here.
is derived from the comminuted-inertinite retention model as shown by the equation below:
(Equation 8)
Where:
- is the fraction of biochar comminuted to mobile fines (sub-0.075 mm) per comminution or recycling round.
- is the number of comminution rounds over the 200-year horizon for the placement band.
follows from element service life, codified in design standards and documented replacement-interval data. Design working lives under EN 1990:2023 are 50 years for common buildings, 100 years for monumental structures and bridges, and 25 years for agricultural buildings; foundations are frequently left in situ. For asphalt, the driver is the milling and resurfacing interval, roughly 15 to 25 years47, rather than the 40-year pavement design-life label in Table 1, because the biochar is comminuted at each resurfacing event. The most conservative (highest) figure for the intended material usage is taken.
Table A6: Comminution rounds N over the 200-year horizon, by placement band.
Band | Service life (sourced) | N over 200 yr |
|---|---|---|
Concrete structural or foundation | 50 to 100+ yr; often left in situ (EN 1990:2023) | ~0 to 2 |
Concrete above-ground element | ~50 yr (EN 1990:2023) | ~3 to 4 |
Concrete thin element (facade, paving, tile) | ~20 to 25 yr (EN 1990:2023) | ~8 to 10 |
Asphalt Sub-Surface | ~15 to 25 yr milling interval | ~7 to 13 |
The Reclaimed Asphalt Pavement (RAP) multiple-recycling literature shows the binder degrades cycle-on-cycle48, so later asphalt cycles are downcycling rather than re-laying, but this does not reduce , because the biochar is comminuted at each event regardless.
, no study measures biochar carbon retention through actual asphalt or concrete recycling and this represents a gap in the current literature. As such, is inferred from the fines (sub-0.075 mm) generated per processing round in the aggregate-recycling literature:
- Asphalt (RAP milling and crushing): roughly 5 to 10% passing the 200 (0.075 mm) sieve per round49, so approximately 0.05 to 0.10.
- Concrete, coarse crush: the sub-0.075 mm fraction is usually minimal, and the biochar stays bound in coarse re-encapsulated aggregate50, so 0.02 to 0.05. This is the physical basis for treating concrete inertinite retention as near-complete for thick elements.
- Concrete, fine crush (thin elements, repeated crushing): fine recycled aggregate carries roughly 4.86 times the sub-0.075 mm crush dust of natural sand51, and repeated crushing produces progressively finer distributions52, so approximately 0.05 to 0.10.
The high end of each range is taken because biochar is more friable than mineral aggregate and the dispersed fraction is untraceable.
Applying Equation 8 across the sourced parameter ranges of gives: concrete structural (f_disp 0.03 to 0.05, N 1 to 2) roughly 0 to 10%; concrete above-ground (0.04 to 0.05, N 3.5 to 4) roughly 13 to 19%; asphalt base (0.05 to 0.075, N 7) roughly 30 to 42%; concrete thin (0.06 to 0.08, N 9 to 10) roughly 43 to 57%; and asphalt binder (0.075 to 0.10, N 10 to 13) roughly 63 to 65%. These model outputs cluster into four risk bands shown in Table . The Module adopts one durability discount per band; the Table below maps each net score and risk rating to that discount and to the representative placement and parameter basis behind it.
Table A7: Durability discount U by risk band.
Net score | Risk rating | Representative placement, and parameter basis | |
|---|---|---|---|
0 to 3 | Low | 10% | Concrete structural or foundation; N ~0 to 2 (EN 1990:2023), minimal coarse-crush fines50 |
4 to 8 | Moderate | 30% | Above-ground concrete; asphalt base course; N ~3 to 7 (EN 1990:2023^49), RAP-fines proxy49 |
9 to 14 | High | 60% | Thin concrete; asphalt binder course; N ~8 to 13 (EN 1990:2023^49), elevated fines51,52 |
15 or more | Very High | 90% (or ineligible) | Extreme dispersal, or worst-case default for un-characterized projects |
Gating (G1; G3 unmitigated) | Ineligible | 100% | Surface asphalt and seal coats (full dispersal, Applicability Section); unmitigated clinker reprocessing (thermal destruction) |
Relevant Works
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Contributors

